C F C RECLAIMATION AND RECYCLING SERVICE INC -- HYDROGEN SULFIDE, PART B -- 6830-01-331-9024
===================== Product Identification ===================== Product ID:HYDROGEN SULFIDE, PART B MSDS Date:09/01/1996 FSC:6830 NIIN:01-331-9024 Status Code:A Kit Part:Y === Responsible Party === Company Name:C F C RECLAIMATION AND RECYCLING SERVICE INC Address:318 N TREADAWAY Box:560 City:ABILENE State:TX ZIP:79604 Country:US Info Phone Num:9150-675-5311 FAX: 915-675-5324 Emergency Phone Num:9150-675-5311 FAX: 915-675-5324 CAGE:0XXK5 === Contractor Identification === Company Name:C F C RECLAIMATION AND RECYCLING SERVICE INC Address:318 N TREADAWAY Box:560 City:ABILENE State:TX ZIP:79604 Country:US Phone:9150-675-5311 FAX: 915-675-5324 CAGE:0XXK5 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGEN SULFIDE (SARA 302/313) (CERCLA), PER TIR:9.0PPM (MIN) AND 11.0PPM(MAX)BY VOLUME CAS:7783-06-4 RTECS #:MX1225000 Fraction by Wt: SEE ING Other REC Limits:NONE RECOMMENDED OSHA PEL:C, 20 PPM ACGIH TLV:10 PPM/15 STEL; 9596 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL HIGHLY TOXIC.IRRIT TO MUC TISSUE,MEMBRANE,CONJ OF EYE.CONT EXPO RENDER OLFACTORY SENSORS INOPERATIVE.RX W/ENZYMES IN BLOODSTREAM INHIBIT CELL RESPIRATION-RESULT IN PULM PARALYSIS,SUDDEN COLLAPSE ,DEATH.THIS OVERSHADOWS IRRIT EFFECT WHIHC @WORST WILL CAUSE PULM EDEMA/CONJ LESIONS. Explanation of Carcinogenicity:PER MSDS:HYDROGEN SULFIDE NOT LISTED IN AIRC/NTP/OSHA AS CAR OR POTENTIAL CARCINOGEN. Effects of Overexposure:CONTD EXPO TO LOW(15-50OPPM)CONC WILL GENERALLY CAUSE IRRIT TO MUC MEBM & CONJ OF EYE.MAY ALSO CAUSEHEAD,DIZZ,NAU.HI CONC(200-300PPM)CAN RESULT IN RESP ARREST LEAD TO COMA/UNCONSC.EXPO FOR >30MINS @CO NC OF >700PPM HAVE BEEN FATAL.CONT INHALOF LOW CONC MAY CAUSE OLFACTORY FTG/PARALYSIS-RENDER DETECTION BY ODOR INFFECTV Medical Cond Aggravated by Exposure:PERSONS IN ILL HEALTH WHERE SUCH ILLNESS WOULD BE AGGRAVATED BY EXPO TO HYDROGEN SULFIDE SHOULD NOT BE ALLOWED TO WORK W/OR HANDLE THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:PROMPT MED ATTN MANDATORY IN ALL OVEREXPO CASES.RESCUERS SHOULD BE EQUIP W/SCBA & COGNIZ OF FIRE/EXPLO HAZ.RESCUERS SHOULD RECOGNIZE HAZ OF OVEREXPO DUE TO OLFACTORY FTG.INHAL:EXT FIRE HAZ DUE TO FLAM M.AVOID USE OF RESCUE EQPMT WHICH MIGHTCONTAIN IGN SOURCES/CAUSE STATIC DISCHARGE.MOVE VICTIM TO UNCONTAM AREA.STOP BREATH GIVE ASSIST RESP;OXY/MIX OF 5%CO2 IN OXY SHOULD BE ADMIN BY QUAL PER(SUPPLE) ===================== Fire Fighting Measures ===================== Flash Point:NA-GAS Autoignition Temp:Autoignition Temp Text:NA Lower Limits:4.0 Upper Limits:44.0 Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL OR WATER SPRAY. Fire Fighting Procedures:SHUT OFF FLOW OF GAS.COOL SURROUNDING FIRE-EXPO CNTNRS W/WATER SPRAY.FIRE FIGHTERS SHOULD USE SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:WILL EXPLO/BURN OVER WIDE RANGE OF MIX IN AIR.BECOMES DNGRSLY RX WHEN MIX W/CONC HNO3/OTH STRONG OXID(H2SO4).VAP COMBUST SPONT WHEN MIX W/CL2,OF2,NF3.SLIGHT(SU) ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL PERSONS.USE APPROP PROT EQPMT.LEAK IN USER EQPMT BE CERTAIN TO PURGE PIPE W/INERT GAS PRIO TO REPAIRS;LEAK IN CNTNR/VALV CONTACT SUPPL/CALL EMERG PHONE#. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:USE ONLY IN WELL VNETI AREA.VAL PROT CAP MUST REMAIN IN PLACE UNLESS CNTNR SECURE W/VAL OUTLET PIPE TO USER PT.DONT DRAG/SLIDE/ROLL CYL-USE HND TRUCK Other Precautions:USE PRESS RED REG WHEN CONNECT CYL TO LOEWR PRESS(<750PSIG)PIP/SYS.DONT HEAT TO INCR DISCHARGE RATE.USE CHECK VALV/TRAP IN DISCHARGE LINE-PREVENT HAZ BACK FLOW INTO CYL.STORE UPRIGHT/FIRMLY IN PLACE A WAY FRM HEAV TRAF/EMERG EXIT.NO IGN SOUC ============= Exposure Controls/Personal Protection ============= Respiratory Protection:POSITIVE PRESSURE AIR LINE W/MASK OR SELF-CONTAINED BREATHING APPARATUS SHOULD BE AVAILABLE FOR EMERG USE. Ventilation:HOOD W/FORCED VENTI.LOC EXHAU-TO PREVENT ACCUMULATION ABOVE TWA. Protective Gloves:NEOPRENE OR BUTYL RUBB,PVC,POLYETHYLENE Eye Protection:SAF GOGGLES OR GLASSES Other Protective Equipment:SAF SHOES,SAF SHOWERS,EYEWASH "FOUNTAIN". Work Hygienic Practices:ADDN RECOMMENDATION:P-1,G-12 FRM COMPRESS GAS ASSOC.EARTH-GROUND/BOND LINE/EQPMT.ELECTRIC EQPMT-NON-SPARK/EPXLO PROOF. Supplemental Safety and Health 1STAID:GET IMMED MED HELP.FURTHER TREAT-SYMPT/SUPP.EYE:PERS W/POT EXPO SHOULDNT WEAR CONTACT LENS.FLUSH W/LOTS OF H2O.PART EYELIDS W/FINGERS TO ASSURE COMPELTE FLUSH.CONT @LEAST 15MINS. NSN:MIXTURE OF NITROGEN F& HYDROGEN SULFIDE,SEE PNIND:A FOR NITROGEN. FIRE/EXPL:SLIGHTLY HEAVIER THAN AIR-ACCUM IN LOW AREA,TRAVEL/IGN ================== Physical/Chemical Properties ================== HCC:G8 Boiling Pt:B.P. Text:-76F,-60C Melt/Freeze Pt:M.P/F.P Text:-117F,-83C Decomp Temp:Decomp Text:NP Vapor Pres:267PSIA Vapor Density:.091LB/FT3 Spec Gravity:1.21 pH:NP Viscosity:NP Evaporation Rate & Reference:NA (GAS) Solubility in Water:SOLUBLE Appearance and Odor:SHIP/STORE AS LIQ UNDER OWN VAP PRESSURE.VAP COLORLESS W/CHARAC ROTTEN EGG ODOR Percent Volatiles by Volume:NP Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONC NITRIC ACID,CHLORINE,NITROGEN TRIFLUORIDE,OXYGEN DIFLUORIDE,OTHER STRONG OXIDIZING AGENTS.HARD STEELS,CORR METALS. Stability Condition to Avoid:AVOID HEAT/FLAME/OTHER IGN SOURCES.PROTECT FRM PHYS DMG.DONT ALLOW TEMPS WHERE STORE >125F/52C. Hazardous Decomposition Products:OXIDES OF SULFUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DONT ATTEMPT TO DISPO WASTE/UNUSE.RETRN IN SHIP CNTNR W/PROP LABEL/VALV OUTLET PLUGS/CAPS ON/VAL PROT IN PLACE.EMERG DISPO ASSIST CONTACT SUPPL/EMERG PHONE LISTED.GAS CYL SHOULDNT BE REFILL EXCEPT BY QUAL PRODUCERS OF COMPRESS GAS-VIOL OF FED LAW. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.