MALLINCKRODT BAKER INC. SUB OF MALLINCKRODT CHEMICAL -- BORIC ACID -- 6810-00-824-9090
===================== Product Identification ===================== Product ID:BORIC ACID MSDS Date:11/17/1999 FSC:6810 NIIN:00-824-9090 Status Code:A === Responsible Party === Company Name:MALLINCKRODT BAKER INC. SUB OF MALLINCKRODT CHEMICAL Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:908-859-2151 Resp. Party Other MSDS Num.:MSDS NO: B3696 Preparer's Name:STRATEGIC SERVICES DIV Chemtrec Ind/Phone:(800)424-9300 CAGE:70829 === Contractor Identification === Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 Company Name:PHOENIX INDUSTRIES INC Address:1519 CHAMBERLAYNE PARKWAY Box:City:RICHMOND State:VA ZIP:23222 Country:US Phone:804-264-5183/FAX: 264-5535 Contract Num:SP0450-00-M-D662 CAGE:0YED2 ============= Composition/Information on Ingredients ============= Ingred Name:BORIC ACID CAS:10043-35-3 RTECS #:ED4550000 = Wt:100. ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 = 2660 MG/KG (RAT) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALE: CAUSES IRRITATION TO THE MUSOUS MEMBRANES OF THE RESPIRATORY TRACT. MAY BE ABSORBED FROM THE MUCOUS MEMBRANES. SKIN: CAUSES SKIN IRRITATION. NOT SIGNIFICANTLY ABSORBED THROUGH THE INTACT SKIN. READILY ABSORBED THROUGH DAMAGED OR BURNED SKIN. EYE: CAUSES IRRITATION, REDNESS & PAIN. CHRONIC: PROLONGED ABSORPTION CAUSES WEIGHT LOSS, VOMITING, DIARRHEA, SKIN RASH, CONVULSIONS & AMEMIA. LIVER & PARTICULARLY THE KIDNEYS MAY BE SUSCEPTIBLE. Explanation of Carcinogenicity:NONE LISTED. Effects of Overexposure:INHALATION: MAY BE ABSORBED FROM THE MUSOUS MEMBRANES, & DEPENDING ON THE AMOUNT OF EXPOSURE COULD RESULT IN THE DEVELOPMENT OF NAUSEA, VOMITING, DIARRHEA, DROWSINESS, RASH, HEADACHE, FALL IN BODY TEM P. , LOW BLOOD PRESSURE, RENAL INJURY, CYANOSIS, COMA & DEATH. INGESTION: SYSMPTOMS PARALLEL ABSORPTION VIA INHALATION. ALULT FATAL DOSE REPORTED AT 5 TO > 30 GRAMS. SKIN: SYMPTOMS OF SKIN ABSORPTION PARALLEL INHALATION & INGESTION. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS OR EYE PROBLEMS, OR IMPAIRED LIVER, KIDNEY OR RESPIRATORY FUNCTION MAY BE MORE SUSECPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN. INGESTION: INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. SKIN: REMOVE ANY CONTAMINATED CLOTHING. WASH SKIN WITH SOAP OR MILD DETERGENT & WATER FOR AT LEAST 15 MINS. GET MEDICAL ATTENTION IF I RRITATION DEVELOPS OR PERSISTS. WASH CLOTHING BEFORE REUSE. EYE: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINS, LIFTING UPPER/LOWER EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IMMED IATELY. ===================== Fire Fighting Measures ===================== Flash Point:NOT A FIRE HAZAR Autoignition Temp:Autoignition Temp Text:NONE P Lower Limits:NONE PROVIDE Upper Limits:NONE PROVIDE Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:IN THE EVENT OF A FIRE, WEAR FULL PROTECTIVE CLOTHING & NIOSH-APPROVED SELF CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE PRESURE DEMAND OR OTHER POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:A MIXTURE OF POTASSIUM AND BORIC ACID MAY EXPLODE ON IMPACT. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. SPILLS: PICK UP & PLACE IN A SUITABLE CONTAINER FOR RECLAMATION OR DISPOSAL, USING A METHOD THAT DOES NOT GENERATE DUST . Neutralizing Agent:NONE PROVIDED BY MFR. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLOSED CONTAINERS IN A COOL, DRY AREA. CARBON STEEL OR ALUMINUM CONTAINERS ARE SUITABLE FOR STORAGE. STAINLESS STEEL IS NEEDED FOR MOIST CONDITIONS. AVOID CONTACT ESPECIALLY WHEN SKIN IS CUT OR ABRAIDED. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESID Other Precautions:NONE PROVIDED BY MFR. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE EXPOSURE LIMIT IS EXCEEDED, A HALF-FACE DUST/MIST RESPIRATOR MAY BE WORN FOR UP TO TEN TIMES THE EXPOSURE LIMIT OR THE MAXIMUM USE CONCENTRATION SPECIFIED BY THE APPROPRIATE REGULATORY AGENCY O R RESPIRATOR SUPPLIER, WHICHEVER IS LOWEST. A FULL-FACE PIECE DUST/MIST RESPIRATOR MAY BE WORN UP TO 50 TIMES THE EXPOSURE LIMIT. FOR EMERGENCIES OR INSTANCES W Ventilation:A SYSTEM OF LOCAL &/OR GENERAL EXHAUST IS RECOMMENDED TO KEEP EMPLOYEE EXPOSURES BELOW THE AIRBORNE EXPOSURE LIMITS. Protective Gloves:GLOVES RECOMMENDED. Eye Protection:CHEMICAL SAFETY GOGGLES. Other Protective Equipment:EYEWASH FOUNTAIN AND QUICK-DRENCH FACILITIES IN WORK AREA. LAB COAT, APRON OR COVERALLS. Work Hygienic Practices:USE GOOD HOUSEKEEPING PRACTICES TO PREVENT ACCUMULATION OF DUST & FOLLOW SOUND CLEANING TECHNIQUES THAT WILL KEEP AIRBORNE PARTICULATES AT A LOW LEVEL. WASH HANDS AFTER HANDLING THIS MATERIAL. Supplemental Safety and Health . ================== Physical/Chemical Properties ================== HCC:C3 Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:=169.C, 336.2F Decomp Temp:Decomp Text:NONE PROVIDED BY MFR. Vapor Pres:2.6 M MHG @ 20 DEG C Vapor Density:NO INFO pH:5.1 AQUEOUS SOL Viscosity:NONE PROVIDED BY MFR. Evaporation Rate & Reference:NO INFO FOUND Solubility in Water:1G/18ML IN COLD WATER Appearance and Odor:WHITE POWDER OR GRANULES, ODORLESS. Percent Volatiles by Volume:0 @ 21 DEG C Corrosion Rate:NONE PROVIDED BY MFR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES POTASSIUM, ACETIC ANHYDRIDE, ALKALIS, CARBONATES, AND HYDROXIDES. Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE & STORAGE. IF MOISTURE IS PRESENT, BORIC ACID CAN BE CORROSIVE TO IRON. Hazardous Decomposition Products:LOSES CHEMICALLY COMBINED WATER UPON HEATING, FORMING METABORIC ACID (HBO2) AT 212 TO 221 DEG F, THEN PYROBORIC ACID (H2B4O7) AT 285 TO 320DEG F, & BORIC ANHYDRIDE AT HIGHER TEMPERATURES. Conditions to Avoid Polymerization:WILL NOT OCCUR =================== Toxicological Information =================== Toxicological Information:INVESTIGATED AS A MUTAGEN, TUMORIGEN, REPRODUCTIVE EFFECTOR. ===================== Ecological Information ===================== Ecological:THE EC50/48-HOUR VALUES FOR DAPHNIA ARE OVER 100 MG/L. THIS MATERIAL MAY BE TOXIC TO AQUATIC LIFE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR RECYCLING SHOULD BE MANAGED IN AN APPROPRIATE & APPROVED WASTE DISPOSAL FACILITY. PROCESSING, USE OR CONTAMINATION OF THIS PRODUCT MAY CHANGE THE WASTE MANAGEM ENT OPTIONS. STATE & LOCAL DISPOSAL REGULATIONS MAY DIFFER FROM FEDERAL REGULATIONS. DISPOSE OF CONT AINER & UNUSED =================== MSDS Transport Information =================== Transport Information:NOT REGULATED. ===================== Regulatory Information ===================== Federal Regulatory Information:ON TSCA INVENTORY LIST. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.