CURTIN MATHESON SCIENTIFIC INC -- SULFURIC ACID 96% -- 6810-00-146-7520
===================== Product Identification ===================== Product ID:SULFURIC ACID 96% MSDS Date:10/21/1986 FSC:6810 NIIN:00-146-7520 === Responsible Party === Company Name:CURTIN MATHESON SCIENTIFIC INC Address:9999 VETERANS MEMORIAL DR Box:1546 City:HOUSTON State:TX ZIP:77251-1546 Country:US Info Phone Num:713-820-9898 Emergency Phone Num:713-820-9898 CAGE:15481 === Contractor Identification === Company Name:CURTIN MATHESON SCIENTIFIC INC Address:9999 VETERANS MEMORIAL DR Box:1546 City:HOUSTON State:TX ZIP:77038-2499 Country:US Phone:713-820-9898 CAGE:15481 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID (SARA III) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 96% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50, RAT (ORAL) 2140 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:UNKNOWN IARC:UNKNOWN OSHA:NO Health Hazards Acute and Chronic:INHALATION PRODUCES DAMAGING EFFECTS ON MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT MAY CAUSE LUNG EDEMA. SWALLOWING MAY CAUSE SEVERE BURNS OF THE MOUTH,THROAT,STOMACH, LEADING TO DEATH.CAN CAUSE SORE THROAT,VOMITING,DIARRHEA. SKIN CONTACT:CORROSIVE. SYMPTONS OF REDNESS,PAIN, & SEVERE BURNS CAN OCCUR. Effects of Overexposure:LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE. MAY BE FATAL IF SWALLOWED. INHALATION MAY CAUSE LUNG DAMAGE. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS OR EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF DIFFICULTY BREATHING, GIVE OXYGEN. CALL PHYSICIAN. INGESTION: DO NOT INDUCE VOMITING. GIVE LARGE QUANTITIES WATER/MILK. CALL PHYSICIAN IMMEDEDIATELY. SKIN: FLUSH SK IN WITH PLENTY OF WATER FOR AT LEAST 15MINUTES. REMOVE CLOTHS/SHOES/CALL A PHYSICIAN. EYES: FLUSH WITH WATER 15 MINUTES, LIFTING LOWER/UPPER EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:DRY CHEMICAL,FOAM OR CARBON DIOXIDE. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND MODE. Unusual Fire/Explosion Hazard:SUBSTANCE IS A STRONG OXIDIZER AND ITS HEAT OF REACTION WITH REDUCING AGENTS OR COMBUSTIBLES MAY CAUSE IGNITION. REACTS WITH MOST METALS RELEASING HYDROGEN GAS. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE/COVER LEAKING OR SPILLED LIQUID WITH DIRT, VERMICULITE, KITTY-LITTER OR OTHER INERT ABSORBENT. COVER SPILL WITH SODIUM BICARBONATE OR SODA ASH & MIX. CLEAN UP PERSONNEL REQUIRE PROTECTIVE CLOTHIN G & RESPIRATORY PROTECTION FROM VAPORS/MISTS. Neutralizing Agent:SODA ASH OR SODIUM BICARBONATE ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL/DRY/VENTILATED STORAGE AREA WITH ACID RESISTANT FLOORS & GOOD DRAINAGE. PROTECT FROM PHYSICAL DAMAGE. KEEP OUT OF DIRECT SUNLIGHT Other Precautions:KEEP AWAY FROM HEAT,WATER,AND INCOMPATIBLE MATERIALS. DO NOT WASH OUT CONTAINER AND USE IT FOR OTHER PURPOSES. WHEN DILUTING, ALWAYS ADD THE ACID TO WATER, NEVER ADD WATER TO THE ACID. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE TLV IS EXCEEDED A FULL FACEPIECE CHEMICAL CARTRIDGE RESP. MAY BE WORN, IN GENERAL, UP TO 100 TIMES THE TLV OR THE MAXIMUM USE CONCENTRATION SPECIFIED BY THE RESP. SUPPLIER, WHICHEVER IS LESS, O R AIRLINED HOOD MAY BE WORN. Ventilation:A SYSTEM OF LOCAL AND/OR GENERAL EXCHANGE IS RECOMMENDED TO KEEP EMPLOYEE EXPOSURE BELOW AIRBORNE EXPOSURE LIMITS. Protective Gloves:IMPERVIOUS Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES Other Protective Equipment:PROTECTIVE CLOTHING, BOOTS, LAB COAT, APRON OR COVERALLS FULL FACE SHIELD. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING Supplemental Safety and Health THIS SUBSTANCE IS CLASSIFIED AS A POSION UNDER THE FEDERAL CAUSTIC POSION ACT. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:590F,310C Melt/Freeze Pt:M.P/F.P Text:6F,-14C Vapor Pres:1@146 C Vapor Density:<0.3 @25 C Spec Gravity:1.84 Evaporation Rate & Reference:NO INFORMATION FOUND Solubility in Water:COMPLETE Appearance and Odor:COLORLESS, OILY LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER,BASES,ORGANIC MATERIAL, HALOGENS, METAL ACETYLIDES,OXIDES AND HYDRIDES, STRONG OXIDIZING & REDUCING AGENTS & OTHER Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:TOXIC FUMES OF OXIDES OF SULFUR. WILL REACT WITH WATER OR STEAM TO PRODUCE TOXIC AND CORROSIVE FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:NEUTRALIZED WASTE MAY BE CONTAINERIZED AND DISPOSED IN A RCRA APPROVED WASTE DISPOSAL FACILITY. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.