FISHER SCIENTIFIC, CHEMICAL DIV. -- CALCIUM CHLORIDE,C 77 -- 6810-00-237-2934
===================== Product Identification ===================== Product ID:CALCIUM CHLORIDE,C 77 MSDS Date:06/30/1994 FSC:6810 NIIN:00-237-2934 === Responsible Party === Company Name:FISHER SCIENTIFIC, CHEMICAL DIV. Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100/800-424-9300(CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:CALCIUM CHLORIDE CAS:10043-52-4 RTECS #:EV9800000 Fraction by Wt: >96% Other REC Limits:TWA 5 MG/M3 MALLINCK Ingred Name:CALCIUM HYDROXIDE CAS:1305-62-0 RTECS #:EW2800000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:5 MG/M3; 9495 Ingred Name:MAGNESIUM SALT Other REC Limits:NONE RECOMMENDED Ingred Name:ALKALI SALTS Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS 1000 MG/KG. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY & GI TRACTS. ACUTE- INHALE:DUST MAY CAUSE IRRITATION. SKIN:CORROSIVE. MAY CAUSE SEVERE IRRITATION, BLISTERING. EYE:MAY CAUSE PAIN & INJURY. ORAL:MAY CAUSE ABDOMIN AL SPASMS & NAUSEA. FATAL DOSE IS ESTIMATED TO BE 30 GRAMS. CHRONIC- MAY CAUSE DERMATITIS, PERFORATION OF NASAL SEPTUM. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, PAIN, DERMATITIS, COUGHING, NOSE BLEED, ULCERATION, REDNESS, CARDIOVASCULAR IRREGULARITIES Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING DISEASES OF THE EYE, SKIN, RESPIRATORY TRACT MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYE:FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. GET PROMPT MEDICAL ATTENTION. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. ORAL:DO NOT INDUCE VOMITING. IF VOMITING OCCURS, KEEP HEAD LOWER THAN HIPS TO HELP PREVENT ASPIRATION. GET MEDICAL ATTENTION IMMEDIATELY. SKIN:WASH WITH SOAP & WATER. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. MOVE CONTAINER FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK. Unusual Fire/Explosion Hazard:CORROSIVE VAPORS MAY FORM. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT TOUCH SPILLED MATERIAL. STOP LEAK IF YOU CAN DO IT WITHOUT RISK. TAKE UP SPILL WITH SAND. PICK UP SMALL DRY SPILL WITH DRY SHOVEL. TRANSFER TO A CONTAINER AND COVER FOR LATER DISPOSAL. AVOID CR EATING DUST. WASH SPILL AREA. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN DRY PLACE AWAY FROM MOISTURE & INCOMPATIBLES. KEEP CONTAINER TIGHTLY CLOSED. DO NOT CONSUME FOOD, DRINK WHILE WORKING WITH THIS MATERIAL. Other Precautions:DO NOT RAISE DUST. AVOID CONTACT WITH EYES, SKIN OR CLOTHING. AVOID INHALATION OF DUST. WASH THOROUGHLY AFTER HANDLING MATERIAL. KEEP OUT OF REACH OF CHILDREN. OBEY HAZARD WARNING OF LABEL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. IF AIRBORNE CONCENTRATION IS HIGH, WEAR A NIOSH-APPROVED DUST RESPIRATOR OR DUST MASK. Ventilation:ADEQUATE Protective Gloves:RUBBER Eye Protection:TIGHT-FITTING SAFETY GOGGLES Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, PROTECTIVE CLOTHING Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health FORMULA CHANGED. FOR PREVIOUS FORMULATION, SEE PNI A, SAME NSN. PH RANGE OF A 5% SOLUTION: 4.5 - 8.5. ================== Physical/Chemical Properties ================== HCC:B3 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=1600.C, 2912.F Melt/Freeze Pt:=777.2C, ######F Spec Gravity:2.15 pH:8.5 5% Evaporation Rate & Reference:NOT RELEVANT Solubility in Water:74.5% @ 68F Appearance and Odor:CUBIC CRYSTALS, GRANULES OR FUSED MASSES, VERY HYGROSCOPIC ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BORIC OXIDE, BROMINE TRIFULORIDE, FURAN-2-PEROXYCABOXYLIC ACID, METALS+MOISTURE, WATER, METHYL VINYL ETHER, ZINC (->H2) Stability Condition to Avoid:MOISTURE Hazardous Decomposition Products:MAY FORM TOXIC AND CORROSIVE CHLORINE GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. 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