GEORGIA GULF CORP -- AMMONIA -- 6810-00F002812
===================== Product Identification ===================== Product ID:AMMONIA MSDS Date:06/24/1986 FSC:6810 NIIN:00F002812 === Responsible Party === Company Name:GEORGIA GULF CORP Address:400 PERIMETER CENTER TER SUITE 595 Box:105197 City:ATLANTA State:GA ZIP:30348-5000 Country:US Info Phone Num:302-836-2100/404-395-4585 Emergency Phone Num:302-836-2100/404-395-4585 Preparer's Name:G.J. KOCH CAGE:49960 === Contractor Identification === Company Name:GEORGIA GULF CORPORATION Address:400 PERIMETER CENTER TER SUITE 595 Box:105197 City:ATLANTA State:GA ZIP:30348 Country:US Phone:504-685-2500/770-395-4500 GOOD# CAGE:49960 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIA, AMMONIUM HYDROXIDE-ANHYDROUS, ANHYDROUS AMMONIA CAS:7664-41-7 RTECS #:BO0875000 Fraction by Wt: 99.5% Other REC Limits:25 PPM OSHA PEL:35 MG/CUM ACGIH TLV:17 MG/CUM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 350 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:SKIN: SEVERE CAUSTIC BURNS. EYES: SEVERE CAUSTIC BURNS & DAMAGE, IRRITATION, TEMPORARY BLINDNESS. INHALATION: SERIOUS RESPIRATORY INJURY, COLLAPSE & IRRITATION, ULCERATED NASAL SEPTUM, CONJUNCTIVA IRR ITATION, CHANGE IN TRACHEA/BRONCHI. DEATH MAY RESULT FROM OVEREXPOSURE. Explanation of Carcinogenicity:NONE Effects of Overexposure:SEVERE CAUSTIC BURNS OF THE SKIN, EYES, MOUTH & ESOPHAGUS, IRRITATION, COMA, CONVULSIONS, BREATHING DIFFICULTY, BLISTERING ======================= First Aid Measures ======================= First Aid:INGESTION: DON'T INDUCE VOMITING. IF CONSCIOUS, GIVE PLENTY OF WATER. INHALATION: REMOVE TO FRESH AIR. RESTORE &/SUPPORT BREATHING IF REQUIRED. KEEP WARM & AT REST. ADMINISTER OXYGEN. EYES: WASH IMMED IATELY W/LARGE AMOUNTS OF WATER, LIFTING LIDS OCCASIONALLY. SKIN: IMMMEDIATELY FLUSH W/WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Lower Limits:16 Upper Limits:25 Extinguishing Media:STOP FLOW GAS, WATER SPRAY/FOG Fire Fighting Procedures:IF GAS LEAKAGE, EVACUATE AREA. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. WEAR SCBA W/FULL FACEPIECE IN POSITIVE PRESSURE MODE & FULL PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:MODERATE FIRE & EXPLOSION HAZARD WHEN EXPOSED TO HEAT/FLAME. VIOLENT RUPTURE CAN OCCUR IF RELIEF VALVES FAIL. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE, ELIMINATE IGNITION SOURCE, VENTILATE. ADJUST LEAKAGE TO DISCHARGE GAS, NOT LIQUID AMMONIA. IF GAS, STOP FLOW. IF SOURCE IS CYLINDER & CAN'T BE STOPPED, REMOVE TO OPEN AIR TO REPAIR/EMPTY. SE E SUPPLEMENTAL DATA. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE CYLINDER/TANKS IN A COOL, WELL VENTILATED, FIREPROOF LOCATION, AWAY FROM OXIDIZING AGENTS, COMBUSTIBLE MATERIALS & SOURCES OF HEAT/IGNITION. Other Precautions:SPECIAL EXTERNAL STORAGE, OUT OF DIRECT SUNLIGHT, IS PREFERRED. DON'T ALLOW WORKERS HANDLING AMMONIA TO WEAR CONTACT LENSES. PREPLACEMENT MEDICAL EXAMINATION IS RECOMMENDED FOR WORKERS. PROVIDE TRAINI NG FOR WORKIERS ON SAFE HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE ANY NIOSH/MSHA APPROVED SCBA/SUPPLIED-AIR RESPIRATOR. Ventilation:LOCAL EXHAUST TO MEET TLV. MECHANICAL (GENERAL) RECOMMENDED. IN BUILDINGS USE EXPLOSION-PROOF ELECTRICAL SERVICES. Protective Gloves:IMPERVIOUS Eye Protection:SAFETY GOGGLES Other Protective Equipment:RUBBER SUIT, BOOTS, APRON, FACE SHIELDS (EIGHT-INCH MINIMUM) Work Hygienic Practices:REMOVE & LAUNDER CONTAMINATED CLOTHING. THAW FROZEN CLOTHING BEFORE REMOVAL. Supplemental Safety and Health SPILL PROCEDURE: GAS MAY BE DISCHARGED INTO COLD WATER FOR COLLECTION. DON'T DIRECTLY DISCHARGE SOLUTION TO SEWERS/WATERWAYS. IF LIQUID, ALLOW TO VAPORIZE. DON'T NEUTRALIZE W/ACID. NOTE: AN OPEN BOTTL E OF CONCENTRATED HYDROCHLORIC ACID CANBE USED TO DETECT SMALL LEAK SOURCES. APPEARANCE: CAN BE LIQUID UNDER PRESSURE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-28F Melt/Freeze Pt:M.P/F.P Text:-108F Vapor Pres:4800 Vapor Density:0.6 Spec Gravity:0.62 pH:11.7 Solubility in Water:51G/100G Appearance and Odor:COLORLESS GAS W/PENETRATING, EXTREMELY PUNGENT, SUFFOCATING ODOR (SEE SUPP DATA Percent Volatiles by Volume:100/WT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, CALCIUM, HYPOCHLORITE BLEACHES, GOLD, MERCURY, SILVER, HALOGENS Stability Condition to Avoid:SOURCES OF HEAT, FLAME, ELEVATED TEMPERATURES . Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:LIMITED AMOUNTS OF AMMONIA GAS MAY BE RELEASED TO THE ATMOSPHERE UNDER APPROPRIATE CONDITIONS. LIMITED AMOUNTS OF AMMONIA SOLUTION CAN BE HIGHLY DILUTED W/WATER FOR DISCHARGE. DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.