MALLINCKRODT INC -- RESORCINOL -- 6810-00N035411
===================== Product Identification ===================== Product ID:RESORCINOL MSDS Date:09/24/1985 FSC:6810 NIIN:00N035411 === Responsible Party === Company Name:MALLINCKRODT INC Box:M City:PARIS State:KY ZIP:40361 Country:US Info Phone Num:314-982-5000 Emergency Phone Num:314-982-5000 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:RESORCINOL (SARA III) CAS:108-46-3 RTECS #:VG9625000 Fraction by Wt: 100% OSHA PEL:10 PPM;20 PPM STEL ACGIH TLV:10 PPM;20 PPM STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUPP DATA: A MANUAL OF RECOMMENDED PRACTICES", MOST RECENT EDITION, FOR DETAILS. RTECS #:9999999ZZ Ingred Name:OTHER PROTECTIVE EQUIPMENT: DRENCH FACILITIES IN WORK AREA. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL,RAT) 301 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: PROMINENT ROUTE FOR ABSORPTION IN BODY CAUSING IRREGULAR HEART BEAT, METHEMOGLOBINEMIA AND EDEMA. INSIDIOUS IN THAT IRRITATION OF THROAT AND LUNGS IS NOT PRONOUNCED. INGESTION: TOXIC! A POISON TO BLOOD AND NERVES. CAUSES GI UPSET AND LEADS TO DYSPNEA, CYANOSIS & CONVULSIONS. SKIN: STRONG (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: IRRITANT TO SKIN. CAN BE ABSORBED VIA LIQUIDS INTO BODY CAUSING SAME SYMPTOMS AS INGESTION. EYE: STRONG IRRITANT. CAN CAUSE PERMANENT DAMAGE. CHRONIC: MOST SYMPTOMS ARE ACUTE. MATERIAL IS CU RRENTLY UNDER STUDY AS CARCINOGEN. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO EFFECTS OF SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. CALL PHYS IMMED. INGEST: INDUCE VOMIT IMMED BY GIVING 2 GLASSES OF WATER & STICKING FINGER DOWN THROAT. CALL P HYS IMMED. NEVER GIVE ANYTHING BY MOUTHTO AN UNCON PERSON. SKIN: IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS WHILE REMOVING CONTAMD CLTHG & SHOES. WASH CLTHG BEFORE REUSE. CALL PHYS (SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:127F,53C Extinguishing Media:WATER SPRAY, DRY CHEMICAL, ALCOHOL FOAM, OR CARBON DIOXIDE. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CNTNRS COOL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:AS WITH MOST ORGANIC SOLIDS, FIRE IS POSSIBLE AT ELEVATED TEMPERATURES OR BY CONTACT WITH AN IGNITION SOURCE. SEALED CONTAINERS MAY RUPTURE WHEN HEATED. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. CLEAN-UP PERSONNEL REQUIRE PROTECTIVE CLOTHING AND RESPIRATORY PROTECTION FROM DUST. SPILLS: PICK UP AND PLACE IN SUITABLE CONTAINER FOR RECLAMATION OR DISPOSAL IN MET HOD THAT DOES NOT GENERATE DUST. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTAINER, STORED IN COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. SEPARATE FROM ACIDS AND OXIDIZING MATERIALS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED, A NIOSH/MSHA APPRVD DUST/MIST RESP W/CHEM GOGGLES MAY BE WORN, IN GEN, UP TO 10 TIMES TLV. CONSULT RESP SUPP FOR LIMITATIONS. ALTERNATIVELY, A NIOSH/MSHA APPRVD SUPP AIR FULL FACEP IECE RESP/AIRLINE HOOD MAY BE WORN. Ventilation:SYS OF LOC &/OR GEN EXHST IS RECOM TO KEEP EMPLOYEE EXPOS BELOW AIRBORNE EXPOS LIMITS. LOC EXHST VENT IS GEN (SUPP DATA) Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:CHEM WORK GOG & FULL LGTH FSHLD . Other Protective Equipment:WEAR IMPERVIOUS PROT CLTHG, INCL BOOTS, LAB COAT, APRON/COVERALLS TO PVNT SKIN CONT. EYEWASH FOUNTAIN & QUICK- (ING 3) Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH MATERIAL. Supplemental Safety and Health FIRST AID PROC: IMMED. EYE: CALL PHYS. WASH EYES W/PLENTY OF WATER FOR AT LST 15 MINS, LIFTING LOWER & UPPER EYELIDS OCCAS. GET MED ATTN IMMED. VENT: PREF BECAUSE IT CAN CNTRL EMISSIONS OF CONTAM AT I TS SOURCE, PVNTG DISPERSION OF IT INTO GEN WORK AREA. PLEASE REFER TO ACGIH DOCUMENT, "INDUSTRIAL VENTILATION, (ING 2) ================== Physical/Chemical Properties ================== HCC:T4 Boiling Pt:B.P. Text:536F,280C Melt/Freeze Pt:M.P/F.P Text:230F,110C Vapor Pres:1 @ 108F Vapor Density:3.8 Spec Gravity:1.27 Solubility in Water:SOLUBLE Appearance and Odor:WHITE POWDER OR CRYSTALS. MAY HAVE PINKISH CAST. FAINT CHARACTERISTIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, ALKALIES, FERRIC SALTS, ACETANILIDE, ALBUMIN, ANTIPYRINE, CAMPHOR, MENTHOL, SPIRIT NITROUS ETHER, & URETHAN. Stability Condition to Avoid:DISCOLORS ON EXPOSURE TO AIR AND LIGHT (TURNS PINK). Hazardous Decomposition Products:TOXIC GASES AND VAPORS MAY BE RELEASED IN INVOLVED IN FIRE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE DISPOSED IN RCRA APPROVED HAZARDOUS WASTE FACILITY. WARNING! MATERIAL IS HARMFUL IF INHALED OR IS IN CONTACT WITH SKIN. ENSURE COMPLIANCE WITH LOCAL, ST ATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.