MALLINCKRODT INC. SCIENCE PRODUCTS DIVISION -- PENTANE -- 6810-00D005102
===================== Product Identification ===================== Product ID:PENTANE MSDS Date:04/06/1989 FSC:6810 NIIN:00D005102 === Responsible Party === Company Name:MALLINCKRODT INC. SCIENCE PRODUCTS DIVISION Address:PARIS BYPASS Box:M City:PARIS State:KY ZIP:40361 Country:US Info Phone Num:800-354-2050(PRESS 3)/314-982-5000 Emergency Phone Num:800-354-2050/314-982-5000 CAGE:62910 === Contractor Identification === Company Name:FREY SCIENTIFIC Address:100 PARAGON PARKWAY Box:City:MANSFIELD State:OH ZIP:44905 Country:US Phone:419-589-1900 CAGE:6U218 Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:PENTANE CAS:109-66-0 RTECS #:RZ9450000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:600 PPM/750STEL;9495 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO LD50 INFO FOUND. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL:VAP MILD NARCOTIC EFFECT.GREATER EXPO MAY CAUSE UNCONSC & DEATH.INGEST:TENDS TO VAPORIZE WHEN SWALLOWED CAUSING ASPIRATION INTO LUNGS.RESULT CAN BE RAPID FALL IN OXY CONTENT W/ASPHYXIA & CONSEQU ENT BRAIN DMG/CARDIAC ARREST.SKIN:DEFATTING AGENTS,IRRIT.EYE:SPLASHES CAUSES PAIN,REDNESS.CHRONIC:DRY,CRACK SKIN,DERM. Effects of Overexposure:SYMPTOMS OF OVEREXPO MAY INCLUDE DROWSNESS & IRRIT OF RESP PASSAGES. MILD NARCOTIC EFFECT. UNCONSC,DEATH, ASPIRATION INTO LUNGS-RAPID FALL IN OXY CONTENT W/ASPHYXIA & BRAIN DMG/CARDIAC ARREST. SKIN DE FATTING, CRACKING, DRYING, DERMATITIS. Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN DISORDERS OR IMPAIRED RESP FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESHA IR.NOT BREATH GIVE ART RESP.DIFFI BREATH GIVE OXY.CALL DR. INGEST:DO NOT INDUCE VOMIT.GIVE LG QUANT OF WATER.NEVER GIVE ANYTHING BY MOUTH IF UNCONSC.CALL DR IMMED. SKIN:WASH ARE A W/SOAP/WATER.GET MED ADVICE IF IRRIT DEVELOPS. EYE:WASH THOROUGHLY W/RUNNING WATER.GET MED ADVICE IF IRRI DEVELOPS. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:-56F,-49C Autoignition Temp:Autoignition Temp Text:260C Lower Limits:1.4 Upper Limits:8.0 Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE. WATERSPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL. Fire Fighting Procedures:IN EVENT OF FIRE WEAR FULL PROT CLOTH & NIOSH-APPROVED SCBA W/FULL FCPIECE OPERATED IN PRESSURE DEMAND/OTHER +PRESSURE MODE.VAP CAN FLOW ALONG SURFACES (SUPPLE) Unusual Fire/Explosion Hazard:HIGHLY FLAMM LIQUID MUST BE KEPT FRM SPARKS/OPN FLAME/HOT SURFACES/ALL SOURCES OF HEAT/IGN.ABOVE FLASH PT VAP/AIR MIX ARE EXPLO W/IN FLAMM LIMITS NOTED ABOVE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTI AREA OF LEAK/SPILL.REMOVE ALL SOURCES OF IGN.CLEANUP PERSONNEL REQUIRE PROT CLOTH/RESP PROT FRM VAP.SM:MAY BE ABSORBED ON PAPER TOWELS/EVAPORATED IN FUME HOOD.ALLOW ENOUGH TIME FOR FUMES TO CLEA R HOOD THEN IGN PAPER IN SUITABLE LOCATION(SUPPLE) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:CONTACT LENSES SHOULDN'T BE WORN WHEN WORK W/MATL.PROT AGAINST PHYS DMG.STORE IN COOL DRY WELL VENTI AREA AWAY FRM FIRE HAZ.OUTSIDE/DETACH STORAGE PRE Other Precautions:SEPARATE FRM OXIDIZING MATL.BOND/GROUND CNTNR.USE NONSPARK TOOLS.DON'T OPN UNLESS CONTENTS @RM TEMP(72F)/BEL.ALLOW 24HRS TO COOL TO RT.STORAGE/USE AREAS SHOULD BE NO SMOKING AREA.REF:ACGIH DOC:"INDUST RIAL VENTI,MANUAL OF RECOMMENDED PRAC". ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV EXCEEDED A HALF MASK CHEMICAL CARTRIDGE RESP (NIOSH APPROVED) MAY BE WORN UP TO 10X THE TLV OR MAXIMUM USE CONCEN SPECIFIED BY RESP SUPPLIER WHICHEVER IS LESS. Ventilation:SYS OF LOC &/OR GEN EXHAU RECOMMENDED TO KEEP WORKER EXPO BELO AEL.LOC EXHAU VENTI PREFER-CAN CNTRL EMISSIONS OF (SUPPL) Protective Gloves:RUBB, NEOPRENE GLOVES. Eye Protection:CHEM SAF GOGG &/OR FULL FCSHIELD. Other Protective Equipment:EYEWASH FOUNTAIN,QUICK-DRENCH FACI IN WORKAREA.IMPERV BOOTS,APRON,COVERALLS AS NEEDED IN AREAS OF UNUSUAL EXPO. Work Hygienic Practices:WASH THOROUGHLY AFT HNDLG. Supplemental Safety and Health FIREFIGHTING:TO DISTANT IGN SOURCE & FLASHBACK. VENTI:CONTAMIN @SOURCE,PREVENT DISPERSION OF IT INTO GEN WORK AREA. SPILL:AWAY FRM COMBUST MATLS.CONTAIN/RECOVER LIQ FOR RECLAMATION WHEN POSSIBLE.LG:CO LLECT AS HAZ WASTE;ABSORB W/VERMIOCULTIE,DRY SAND,EARTH,SIMILAR MATL FOR DISPO. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:96.8F,36.0C Melt/Freeze Pt:M.P/F.P Text:-202F,-130C Vapor Pres:426 @20C Vapor Density:2.5 Spec Gravity:0.631 Evaporation Rate & Reference:28.6 (N-BUTYL ACETATE=1) Solubility in Water:INSOLUBLE. Appearance and Odor:CLEAR, COLORLESS SOLUTION; MILD GASOLINE-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, HEAT, FLAME. Stability Condition to Avoid:HEAT & SOURCES OF IGNITION. Hazardous Decomposition Products:TOXIC GASES & VAP MAY BE RELEASED IF INVOLVED IN FIRE.THERMAL-OXIDATIVE DECOMPO PROD IN AIR CAN INCLUDE OXIDES OF CARBON ==================== Disposal Considerations ==================== Waste Disposal Methods:ATOMIZE IN SUITABLE RCRA APPROVED COMBUSTION CHAMBER/ABSORB W/VERMICULITE,DRY SAND,EARTH,SIMILAR MATL FOR DISPO AS HAZ WASTE IN RCRA APPROVED FACILITY.DO NOT FLUSH TO SEWER.ENSURE COMPLIANCE W/LOC/STA TE/FED REGS. 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