EM SCIENCE -- ACETIC ACID, 55 -- 6810-00N084212
===================== Product Identification ===================== Product ID:ACETIC ACID, 55 MSDS Date:03/03/1994 FSC:6810 NIIN:00N084212 === Responsible Party === Company Name:EM SCIENCE Address:480 DEMOCRAT RD Box:70 City:GIBBSTOWN State:NJ ZIP:08027 Country:US Info Phone Num:609-423-6300 Emergency Phone Num:800-424-9300(CHEMTREC) CAGE:DO242 === Contractor Identification === Company Name:E M SCIENCE DIV OF E M INDUSTRIES INC Address:480 DEMOCRAT ROAD Box:70 City:GIBBSTOWN State:NJ ZIP:08027 Country:US Phone:800-222-0342/609-423-6300 CAGE:63612 Company Name:EM SCIENCE Address:480 DEMOCRAT RD City:GIBBSTOWN State:NJ ZIP:08927 Phone:800-424-9300 (CHEMTREC) CAGE:DO242 ============= Composition/Information on Ingredients ============= Ingred Name:ACETIC ACID (CERCLA) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 100% OSHA PEL:10 PPM ACGIH TLV:10 PPM;15 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SPILL PROC:RISK. TAKE UP & CONTAINERIZE FOR PROPER DISP AS DESCRIBED UNDER DISP. COMPLY W/FED, STATE & LOC REGS (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:ON REPORTING RELS. REFER TO REGULATORY INFO FOR REPORTABLE QTY & OTHER REGULATORY DATA. EM SCIENCE RECS (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:SPILL-X NEUTRALIZERS & ABSORB AGENTS FOR VARIOUS TYPES OF SPILLS. ADDNL INFO ON SPILL-X PRODS CAN BE (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:PROVIDE THRU EM SCIENCE TECHNICAL SERVICE DEPT (609)354-9200. RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:ACID-RESISTANT PROTECTIVE SUIT W/RUBBER BOOTS. SAFETY EQUIPMENT SHOULD BE READILY AVAILABLE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT) 3530 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:CONTACT CAUSES SEVERE BURNS, EYE DAMAGE. VAPOR INHALATION CAUSES LACHRYMATION, SEVERE IRRITATION OF RESPIRATORY PASSAGES; BRONCHITIS, PULMONARY EDEMA AND CHEMICAL PNEUMONITIS MAY OCCUR. MAY BE FATAL I F SWALLOWED. TEST ON LAB ANIMALS INDICATE MATERIAL MAY PRODUCE ADVERSE MUTAGENIC AND REPRODUCTIVE EFFECTS. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:RESPIRATORY CONDITIONS. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. SKIN:IMMEDIATELY FLUSH THOROUGHLY W/LARGE AMOUNTS OF WATER. REMOVE CONTAMINATED CLOTHING & WASH BEFORE REUSE. EYES:IMMEDIATELY FLUSH THOROUGHLY W/ WATER FOR AT LEAST 15 MINUTES. INHAL:REMOVE TO FRESH AIR; GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. INGEST:DO NOT INDUCE VOMITING; GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:109F,43C Lower Limits:5.4% Upper Limits:16% Extinguishing Media:CO*2, DRY CHEMICAL, "ALCOHOL" FOAM, WATER MIST. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:MODERATE FIRE & EXPLOSION HAZARD. VAPOR CAN TRAVEL DISTANCES TO IGNITION SOURCE & FLASH BACK. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA OF ALL UNNEC PERS. WEAR SUITABLE PROT EQUIP LISTED UNDER EXPOS/PERSONAL PROT SECTION. ELIM ANY IGNIT SOURCES UNTIL AREA IS DETERMINED TO BE FREE FROM EXPLO/FIRE HAZS. CONTAIN RELS & ELIM ITS SOURCE, IF THIS CAN BE DONE W/OUT (ING 2) Neutralizing Agent:FOLLOWING EM SCIENCE SPILL-X NEUTRALIZER & ABSORB IS REC FOR THIS PROD: (SUPDAT) ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE ABOVE 62F, BUT AWAY FROM DIRECT HEAT, IGNITION SOURCES & OXIDIZERS. DO NOT BREATHE VAPOR. Other Precautions:DO NOT GET IN EYES ON SKIN OR ON CLOTHING. RETAINED RESIDUE MAY MAKE EMPTY CONTAINERS HAZARDOUS; USE CAUTION! DO NOT TAKE INTERNALLY. HARMFUL IF INHALED. FLAMMABLE LIQUID & VAPOR. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORKPLACE EXPOS LIM(S) OF PROD/ANY COMPONENT IS EXCEEDED, A NIOSH APPRVD AIR SUPPLIED RESP IS ADVISED IN ABSENCE OF PROPER ENVIRON CONTROL. OSHA REGS ALSO PERMIT OTHER NIOSH APPRVD RESPS (NEG PRESS TYPE) UNDER SPECIFIED CNDTNS (SUPDAT) Ventilation:MATERIAL MUST BE HANDLED OR TRANSFERRED IN AN APPROVED FUME HOOD OR W/EQUIVALENT VENTILATION. Protective Gloves:NATURAL RUBBER, NEOPRENE, PVC OR(SUPDAT) Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT) Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER . IMPERVIOUS PROT CLTHG SHOULD BE WORN TO PVNT SKIN CONT. (ING 6) Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health MATLS TO AVOID:CARBONATES. NEUT AGENT:SX0861 - SPILL-X-A ACID SPILL TREATMENT KIT. WASTE DISP METH:& FED REGS. RESP PROT:(SEE YOUR SFTY EQUIP SUPPLIER). ENGINEERING &/OR ADMIN CONTROLS SHOULD BE IMPLE MENTED TO REDUCE EXPOS. PROT GLOVES:EQUIVALENT GLOVES. EYE PROT:& FULL LENGTH FACESHIELD . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:245F,118C Melt/Freeze Pt:M.P/F.P Text:62.1F,16.7C Vapor Pres:11.4 @ 20C Vapor Density:2.07 Spec Gravity:1.049 (H*2O=1) Evaporation Rate & Reference:0.97 (BUTYL ACETATE=1) Solubility in Water:MISCIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID; PUNGENT ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, STRONG ALKALIES, METALS, AMINES, CYANIDES, SULFIDES, CHROMIC ACID, NITRIC ACID, HYDROGEN PEROXIDE, (SUPDAT) Stability Condition to Avoid:HEAT; CONTACT W/IGNITION SOURCES. DILUTED ACID REACTS W/METALS TO PRODUCE FLAMMABLE HYDROGEN GAS. Hazardous Decomposition Products:CO*X. ==================== Disposal Considerations ==================== Waste Disposal Methods:EPA WASTE NUMBERS:D002, D001. SPECIFIED TECHNOLOGY - NEUTRALIZE TO PH 6-9. CONT YOUR LOC PERMITTED WASTE DISP SITE (TSD) FOR PERMISSIBLE TREATMENT SITES. ALWAYS CONT PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE W/ALL CURRENT LOC, STATE(SUPDAT) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.