ALLIED-SIGNAL INC RESEARCH AND TECHNOLOGY -- HYDROCHLORIC ACID -- 6810-00-222-9641
===================== Product Identification ===================== Product ID:HYDROCHLORIC ACID MSDS Date:04/01/1995 FSC:6810 NIIN:00-222-9641 === Responsible Party === Company Name:ALLIED-SIGNAL INC RESEARCH AND TECHNOLOGY Address:101 COLUMBIA RD Box:1139 City:MORRISTOWN State:NJ ZIP:07962-1139 Country:US Info Phone Num:201-455-4157 Emergency Phone Num:201-455-2000 CAGE:0B7T5 === Contractor Identification === Company Name:HONEYWELL INTL INC Address:101 COLUMBIA RD Box:City:MORRISTOWN State:NJ ZIP:07960 Country:US Phone:201-455-2000/800-707-4555 CAGE:0B7T5 Company Name:HONEYWELL INTL INC RESEARCH AND TECHNOLOGY Address:101 COLUMBIA ROAD Box:1053 City:MORRISTOWN State:NJ ZIP:07962-1053 Country:US Phone:973-455-2000 CAGE:0PK95 Company Name:VENUS LABORATORIES INC Address:15571 COMMERCE LANE Box:City:HUNTINGTON BEACH State:CA ZIP:92649 Country:US Phone:714-881-3100 CAGE:0N140 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA 302/313) (CERCLA) CAS:7647-01-0 RTECS #:MW4025000 Fraction by Wt: 28 - 35% Other REC Limits:NONE RECOMMENDED OSHA PEL:C 5 PPM ACGIH TLV:C 5 PPM; 9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 65 - 72% Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV 5 PPM- CEILING. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, TEETH, RESPIRATORY & GI TRACTS. ACUTE- CORROSIVE. INHALE:MAY CAUSE INFLAMMATION, CHOCKING, COUGHING, LUNG DAMAGE. EYE/SKIN:SEVERE BURNS. MAY CAUSE PERMANENT EYE DAMAGE. ORAL: IMMEDIATE PAIN & BURNS OF MOUTH, THROAT, ESOPHAGUS & GI TRACT. MAY BE FATAL. CHRONIC- EROSION OF TEETH, DERMATITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:SEVERE IRRITATION, BURNS, COUGHING, DIFFICULT BREATHING, CHEST PAIN, ABDOMINAL PAIN, NAUSEA, VOMITING, DENTAL EROSION, CHOCKING, BROWNISH OR YELLOW SKIN STAIN, DEEP ULCERATION, EYE DAMAGE, DEATH, CIRC ULATORY COLLAPSE, DERMATITIS Medical Cond Aggravated by Exposure:DAMAGED SKIN, EYE DISORDERS, LUNG/RESPIRATORY SYSTEM DISEASES ======================= First Aid Measures ======================= First Aid:GET MEDICAL CARE IMMEDIATELY IN ALL CASES. EYES/SKIN:IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. KEEP EYELIDS OPEN. TREAT FOR CHEMICAL BURNS IF NECESSARY. INHALATION:REMOVE TO FRESH AIR. PRO VIDE CPR/OXYGEN IF NEEDED. ORAL:IF CONSCIOUS & FREE FROM CONVULSION, DRINK LARGE AMOUNT OF WATER. DO NOT INDUCE VOMITING. DRINK MILK, MILK OF MAGNESIA OR CALCIUM HYDROXIDE. DO NOT TAKE CARBONATES ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:CONTAINER MAY RUPTURE. REACTS WITH MOST METALS FORMING HYDROGEN WHICH CAN EXPLODE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROPER PROTECTIVE EQUIPMENT. VENTILATE AREA. REMOVE IGNITION SOURCES (H2 MAY BE PRESENT). DO NOT RELEASE INTO SOIL, SEWER. NEUTRALIZE WITH SODA ASH/SODIUM BICARBONATE. USE AN ABSORBENT SUCH AS SA ND/VERMICULITE ON SLURRY. TRANSFER TO CONTAINER. Neutralizing Agent:SODA ASH, LIME, SODIUM BICARBONATE ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, WELL-VENTILATED, CORROSION-PROOF AREA, AWAY FROM INCOMPATIBLE MATERIALS. KEEP OUT OF REACH OF CHILDREN. Other Precautions:DANGER! STRONG ACID. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. AVOID BREATHING VAPORS/MIST. USE UNDER THE HOOD WITH ADEQUATE VENTILATION. PROTECT CONTAINERS AGAINST PHYSICAL DAMAGE. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH (NIOSH) APPROVED SELF-CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE PRESSURE MODE WHEN PERMISSIBLE EXPOSURE LIMITS ARE EXCEEDED. Ventilation:PROVIDE GENERAL VENTILATION OR LOCAL EXHAUST TO MEET OSHA PERMISSIBLE EXPOSURE LIMITS (OSHA PEL). Protective Gloves:PVC, NEOPRENE Eye Protection:CHEMICAL SAFETY GOGGLES AND FACE SHIELD Other Protective Equipment:USE RUBBER SPLASH APRON AND RUBBER BOOTS. EYEWASH AND SAFETY SHOWER SHOULD BE LOCATED NEARBY. Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NOTE TO PHYSICIAN:WASH AFFECTED SKIN AREAS WITH A 5% SOLUTION OF SODIUM BICARBONATE. IF INGESTED, THE RISK VERSUS THE BENEFIT OF THE PASSAGE OF A NASO-GASTRIC TUBE IS DEBATABLE. DO NOT GIVE THE EXPOSE D PERSON BICARBONATE TO NEUTRALIZE THE MATERIAL. ================== Physical/Chemical Properties ================== HCC:C1 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:181F - 142F Melt/Freeze Pt:M.P/F.P Text:-87F - -63F Vapor Pres:25-84 @68F Vapor Density:1.27 Spec Gravity:1.16 - 1.18 pH:0.8 1% Evaporation Rate & Reference:<1 (ETHER=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS TO LIGHT YELLOW FUMING LIQUID - SHARP, PUNGENT, IRRITATING ODO Percent Volatiles by Volume:28- 35 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER-REACTIVE MATERIALS SUCH AS ACETIC ANHYDRIDE/SULFURIC ACID, MOST METALS, BASES, AMINES, ESTERS, CYANIDES, CARBONATE Stability Condition to Avoid:EXCESSIVE HEAT Hazardous Decomposition Products:MAY EMIT HYDROGEN CHLORIDE VAPORS OR GAS, CHLORINE, OXIDES OF CHLORINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATORS FOR PROPER DISPOSAL. CONSIDER RECYCLING. NEUTRALIZED WASTE SHOULD BE DISPOSED BY LICENSED DISPOSAL AGENCY. 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