Material Safety Data Sheet
Calcium
ACC# 03840
Section 1 - Chemical Product and Company Identification |
MSDS Name: Calcium
Catalog Numbers:
S71899, S71899-1, S71899ND, S71900, S71900-1, S719001ND, S71901, S71901-1,
S7190111ND, S93154, S93155
Synonyms:
Calcicat; Calcium Metal.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
7440-70-2 |
Calcium |
100 | 231-179-5 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: silver white crystals.
Danger! Reacts violently and/or explosively with
water, steam or moisture. Dangerous when wet. Causes digestive and
respiratory tract irritation with possible burns. Can be explosive
when exposed to heat or flames. May ignite or explode on contact with
moist air. Causes eye and skin irritation and possible burns. Air
sensitive.
Target Organs: Respiratory system, eyes, skin.
Potential Health Effects
Eye:
Causes redness and pain. Causes eye irritation and possible burns.
Skin:
Contact with skin causes irritation and possible burns, especially
if the skin is wet or moist. Causes redness and pain.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. May cause severe respiratory tract irritation and
possible burns.
Chronic:
No information found.
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid. Do NOT allow vi
ctim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Water
Reactive. Material will react with water and may release a flammable
and/or toxic gas. This chemical poses an explosion hazard. Reacts
with water to form explosive hydrogen gas. May ignite or explode on
contact with steam or moist air. May re-ignite after fire is
extinguished.
Extinguishing Media:
Do NOT get water inside containers. Contact professional
fire-fighters immediately. Cool containers with flooding quantities
of water until well after fire is out. DO NOT USE WATER OR FOAM. For
small fires, use dry chemical, soda ash, lime or sand. For large
fires, use dry sand, dry chemical, soda ash or lime or withdraw from
area and let fire burn.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 1; Instability: 2; Special Hazard: -W-
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions. Do
not expose spill to water. Place under an inert atmosphere.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Do not allow water to get into the container because of violent
reaction. Minimize dust generation and accumulation. Avoid contact
with eyes, skin, and clothing. Avoid ingestion and inhalation. Handle
under an inert atmosphere. Store protected from air. Keep from
contact with moist air and steam.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from water. Do not expose to air. Store protected from moisture.
Store under an inert atmosphere.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate ventilation to keep airborne
concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Calcium
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Calcium:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Crystals
Appearance: silver white
Odor: none reported
pH: Not available.
Vapor Pressure: 10 mm Hg @983 deg C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 1484 deg C
Freezing/Melting Point:845 deg C
Decomposition Temperature:Not available.
Solubility: Decomposes.
Specific Gravity/Density:1.54@20°C/4°C
Molecular Formula:Ca
Molecular Weight:40.08
Section 10 - Stability and Reactivity
|
Chemical Stability:
Combines vigorously or explosively with water. May ignite
spontaneously if exposed to air or kept in the presence of moisture.
Conditions to Avoid:
Dust generation, exposure to air, excess heat, exposure to moist air
or water.
Incompatibilities with Other Materials:
Acids, oxidizing agents, carbonates, dinitrogen tetraoxide, halogens,
sulfur, chlorine, chlorine trifluoride, fluorine, air, moisture,
water, water and mixtures containing water (e.g. aqueous solutions,
water).
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, hydrogen gas, calcium oxide,
calcium hydroxide.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 7440-70-2:
EV8500000
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 7440-70-2:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
CALCIUM |
CALCIUM |
Hazard Class: |
4.3 |
4.3 |
UN Number: |
UN1401 |
UN1401 |
Packing Group: |
II |
II |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 7440-70-2 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7440-70-2: immediate, fire.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7440-70-2 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
F
Risk Phrases:
R 15 Contact with water liberates extremely flammable gases.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 8 Keep container dry.
S 43C In case of fire, use limestone powder, sodium chloride or dry
sand (never use water).
WGK (Water Danger/Protection)
CAS# 7440-70-2: 1
Canada - DSL/NDSL
CAS# 7440-70-2 is listed on Canada's DSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
Section 16 - Additional Information
|
MSDS Creation Date: 5/19/1999
Revision #3 Date: 10/03/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.